Detection of hydrocarbons in Titan using high-resolution cross-correlation spectroscopy

arXiv:2609.03975

Maria Coelho, Rafael Rianço-Silva, Diogo Gonçalves, Pedro Machado, Zita Martins

High-resolution cross-correlation spectroscopy (HRCCS) is a powerful technique for detecting molecules whose individual spectral lines are too weak to be identified directly, but its sensitivity is limited by the availability and quality of high-resolution opacity data. Many molecules of atmospheric and astrobiological interest lack complete line lists, restricting traditional template-based searches. In this work, we use Titan as a controlled testbed to develop and validate a new cross-section-based methodology for HRCCS template construction. We analyse K-band CRIRES+ observations of Titan (1.99 - 2.48 μm), and compute cross-correlation functions using both line-by-line and cross-section-based templates. Our analysis recovers known hydrocarbons such as methane (CH4) and acetylene (C2H2), and yields the first HRCCS detection of ethane (C2H6) with a significance of SNRpeak = 5.17 {\pm} 0.07. The ethane detection was made possible exclusively through cross-section-based templates, as no high-resolution line list currently exists for this molecule. These results demonstrate that cross-section-based template construction is a practical and powerful strategy for extending HRCCS to molecules that currently lack reliable line lists, and establish Titan as a benchmark for calibrating molecular detection techniques that can be applied to both solar system and exoplanet atmospheres. Future applications of this approach to other ground-based high-resolution spectrographs, as well as to JWST's highest-resolution modes and next-generation facilities such as the ELT, could significantly expand the inventory of molecules detectable in planetary atmospheres.